1-Isopropyl-4-tosylpiperazin-1-ium trifluoroacetate

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1-Isopropyl-4-tosyl­piperazin-1-ium trifluoro­acetate

In the title compound, C(14)H(23)N(2)O(2)S(+)·C(2)F(3)O(2) (-), the piperazine ring adopts a chair conformation. The crystal packing is stabilized by C-H⋯O and N-H⋯O hydrogen bonds between the cation and anion. The F atoms are disordered over two positions; the site occupancy factors are 0.55 (2) and 0.45 (2).

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4-(2-Meth­oxy­phen­yl)piperazin-1-ium 6-chloro-5-isopropyl-2,4-dioxopyrimidin-1-ide

In the cation of the title salt, C11H17N2O(+)·C7H8ClN2O2 (-), the piperazine ring adopts a distorted chair conformation and contains a positively charged N atom with quaternary character. Its mean plane makes a dihedral angle of 42.36 (8)° with the phenyl ring of its 2-meth-oxy-phenyl substituent. The 2,4-dioxopyrimidin-1-ide anion is generated by deprotonation of the N atom at the 1-position o...

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Crystal structures of 4-phenyl­piperazin-1-ium 6-chloro-5-ethyl-2,4-dioxopyrimidin-1-ide and 4-phenyl­piperazin-1-ium 6-chloro-5-isopropyl-2,4-dioxopyrimidin-1-ide

The title mol-ecular salts, C10H15N2 (+)·C6H6ClN2O2 (-), (I), and C10H15N2 (+)·C7H8ClN2O2 (-), (II), consist of 4-phenyl-piperazin-1-ium cations with a 6-chloro-5-ethyl-2,4-dioxopyrimidin-1-ide anion in (I) and a 6-chloro-5-isopropyl-2,4-dioxopyrimidin-1-ide anion in (II). Salt (I) crystallizes with two independent cations and anions in the asymmetric unit. In the crystal structures of both sal...

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4-Benzhydryl-1-cinnamylpiperazin-1-ium nitrate

In the title compound, C(26)H(29)N(2) (+)·NO(3) (-), the dihedral angle formed by the phenyl rings of the benzhydryl group is 66.18 (9)°. Crystal cohesion is enforced by cation-anion C-H⋯O and N-H⋯O hydrogen bonds.

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1-(4-Fluoro­phen­yl)biguanid-1-ium chloride

The title compound, C(8)H(11)FN(5) (+)·Cl(-), crystallized with a monoprotonated 1-(4-fluoro-phen-yl)biguanidinium cation and a chloride anion in the asymmetric unit. The biguanidium group is not planar [dihedral angle between the two CN(3) groups = 52.0 (1)°] and is rotated with respect to the phenyl group [τ = 54.3 (3)°]. In the crystal, N-H⋯N hydrogen-bonded centrosymmetric dimers are connec...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2007

ISSN: 1600-5368

DOI: 10.1107/s1600536807061570